Avianca is having another sale from Barcelona to Bogota non-stop from €1,491.
These fares book into A class which earns 100% in most Star Alliance programs and gives you 1/5 of distance as PQPs for United. So you would earn 10584 miles and 2117 PQPs.
Here are some links to Trip Reports on Avianca on their Boeing 787 from GRU-BOG
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