Acceptable sale with Avianca from Los Angeles to Barcelona via Bogota. Avianca got rid of Business class in late 2022 and service levels remain at pathetic levels with limited service quality. Here are some links to Trip Reports on Avianca on their Boeing 787 from GRU-BOG but these are pre-Covid reviews. Los Angeles to Bogota segments are operated by Wamos Air using Airbus 330s.
These fares book into A class (XL in Avianca terms) which earns 100% in most Star Alliance programs and gives you 1/5 of distance as PQPs for United. In the case of the sample below BOG-BCN you would earn 17540 miles and 3508 PQPs.
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