Iberia has a decent fare in Premium Economy from Sao Paulo to Barcelona via Madrid. This flight credits nicely to American Airlines and the service is acceptable on the long-haul flight. Here is a Trip Report with Iberia on their Madrid to New York route.
American Airlines Executive Platinum flyers would obtain 24169 LPs, Platinum Pro 19775 LPs, Platinum 17578 LPs, Gold 15380 LPs, Base Members 10986 LPs
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